Author: Baddeley, Thomas C.; Wardell, Solange M. S. V.; Tiekink, Edward R. T.; Wardell, James L.
Title: 1,3-Diphenyl-4,5-dihydro-1H-pyrazol-5-one Cord-id: dg90gulb Document date: 2012_3_10
ID: dg90gulb
Snippet: In the title pyrazolone derivative, C(15)H(12)N(2)O, the five-membered ring is approximately planar (r.m.s. deviation = 0.018 Ã…), and the N- and C-bound benzene rings are inclined to this plane [dihedral angles = 21.45 (10) and 6.96 (10)°, respectively] and form a dihedral angle of 20.42 (10)° with each other. SupraÂmolecular layers are formed in the crystal structure via C—H⋯O and C—H⋯N interÂactions, and these are assembled into double layers by C—H⋯π and π–π interÂactio
Document: In the title pyrazolone derivative, C(15)H(12)N(2)O, the five-membered ring is approximately planar (r.m.s. deviation = 0.018 Ã…), and the N- and C-bound benzene rings are inclined to this plane [dihedral angles = 21.45 (10) and 6.96 (10)°, respectively] and form a dihedral angle of 20.42 (10)° with each other. SupraÂmolecular layers are formed in the crystal structure via C—H⋯O and C—H⋯N interÂactions, and these are assembled into double layers by C—H⋯π and π–π interÂactions between the pyrazole and C-bound benzene rings [ring centroid–centroid distance = 3.6476 (12) Ã…]. The double layers stack along the a axis being connected by π–π interÂactions between the N- and C-bound benzene rings [ring centroid–centroid distance = 3.7718 (12) Ã…].
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