Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

Marchenko, Roman D.; Sukhikh, Taisiya S.; Ryadun, Alexey A.; Potapov, Andrei S.

Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO(3)](n), in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag(2)L(2)} and {Ag(4)L(4)} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)(2)(NO(3))(2)](n) was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO(3))(2)(CH(3)OH)]·0.5CH(3)OH}(n) was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.