Facile Synthesis and Electrochemical Studies of Mn(2)O(3)/Graphene Composite as an Electrode Material for Supercapacitor Application

Mustafa, Ghulam; Mehboob, Gohar; Khisro, Said Nasir; Javed, Muhammad; Chen, Xinman; Ahmed, M. Shafiq; Ashfaq, J. M.; Asghar, G.; Hussain, Shahnwaz; Rashid, Amin ur; Mehboob, Ghazanfar

A simplified sol-gel method that can be scaled up for large-scale production was adopted for the preparation of manganese oxide nanocrystals. Prepared Mn(2)O(3) exhibited micron-sized particles with a nanoporous structure. In the present study, a simple and low-cost strategy has been employed to fabricate nanoporous Mn(2)O(3) with an increased surface area for an electrode/electrolyte interface that improved the conduction of Mn(2)O(3) material. The crystal phase and morphology of the prepared material was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). The prepared electrode materials were deposited on a nickel foam substrate to investigate the electrochemical properties. The galvanostatic charge/discharge (GCD), cyclic voltammetry (CV), and complex impedance studies confirmed excellent specific capacitance and capacitive behavior of the prepared material. The synthesized Mn(2)O(3)/graphene composites exhibited an excellent specific capacitance of 391 F/g at a scan rate of 5 mV/S. Moreover, a specific capacitance of 369 F/g was recorded at a current density of 0.5 A/g using the galvanostatic charge/discharge test. The high porosity of the materials provided a better electrolyte-electrode interface with a larger specific area, thus suggesting its suitability for energy storage applications.