Recent development of two-dimensional metal-organic framework derived electrocatalysts for hydrogen and oxygen electrocatalysis.

Wu, Hengbo; Wang, Jie; Jin, Wei; Wu, Zexing

Developing efficient and low-cost electrocatalysts with unique nanostructures is of great significance for improved electrocatalytic reactions, including the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Two-dimensional (2D) metal-organic frameworks (MOFs) have attracted recent attention because of their unique dimension-related properties, such as ultrathin thickness, large specific surface area, and abundant accessible active sites that can act as good precursors for the derivation of a variety of nanocomposites as active materials in electrocatalysis and energy-related devices. In this review, we present recent developments in 2D MOF-derived nanomaterials for hydrogen and oxygen reactions in overall water-splitting and rechargeable Zn-air batteries. The advantages of various synthetic strategies are summarized and discussed in detail. Finally, we discuss the main challenges and future perspectives of the development of 2D MOF-derived electrocatalysts.